Phase transition in Pr0.5Ca0.5CoO3 and related cobaltites

We present an extensive investigation (magnetic, electric and thermal measurements and X-ray absorption spectroscopy) of the Pr0.5Ca0.5CoO3 and (Pr1-yYy)0.7Ca0.3CoO3 (y=0.0625-0.15) perovskites, in which a peculiar metal-insulator (M-I) transition, accompanied with pronounced structural and magnetic anomalies, occurs at 76 K and 40-132 K, respectively. The inspection of the M-I transition using the XANES data of Pr L3-edge and Co K-edge proofs the presence of Pr4+ ions at low temperatures and indicates simultaneously the intermediate spin to low spin crossover of Co species on lowering the temperature. The study thus definitively confirms the synchronicity of the electron transfer between Pr3+ ions and Co^(3+/4+)O3 subsystem and the transition to the low-spin, less electrically conducting phase. The large extent of the transfer is evidenced by the good quantitative agreement of the determined amount of the Pr4+ species, obtained either from the temperature dependence of the XANES spectra or via integration of the magnetic entropy change over the Pr4+ related Schottky peak in the low-temperature specific heat. These results show that the average valence of Pr3+/Pr4+ ions increases (in concomitance with the decrease of the formal Co valence) below TMI for (Pr0.925Y0.075)0.7Ca0.3CoO3 up to 3.16+ (the doping level of the CoO3 subsystem decreases from 3.30+ to 3.20+), for (Pr0.85Y0.15)0.7Ca0.3CoO3 up to 3.28+ (the decrease of doping level from 3.30+ to 3.13+) and for Pr0.5Ca0.5CoO3 up to 3.46+ (the decrease of doping level from 3.50+ to 3.27+).Comment: 19 pages, 11 figure

On the peak in the far-infrared conductivity of strongly anisotropic cuprates

We investigate the far-infrared and submillimeter-wave conductivity of electron-doped La_(2-x)Ce_xCuO_4 tilted 1 degree off from the ab-plane. The effective conductivity measured for this tilt angle reveals an intensive peak at finite frequency (\nu ~ 50 cm{-1}) due to a mixing of the in-plane and out-of-plane responses. The peak disappears for the pure in-plane response and transforms to the Drude-like contribution. Comparative analysis of the mixed and the in-plane contributions allows to extract the c-axis conductivity which shows a Josephson plasma resonance at 11.7 cm{-1} in the superconducting state.Comment: 4 pages, 4 figures include

Capture on High Curvature Region: Aggregation of Colloidal Particle Bound to Giant Phospholipid Vesicles

A very recent observation on the membrane mediated attraction and ordered aggregation of colloidal particles bound to giant phospholipid vesicles (I. Koltover, J. O. R\"{a}dler, C. R. Safinya, Phys. Rev. Lett. {\bf 82}, 1991(1999)) is investigated theoretically within the frame of Helfrich curvature elasticity theory of lipid bilayer fluid membrane. Since the concave or waist regions of the vesicle possess the highest local bending energy density, the aggregation of colloidal beads on these places can reduce the elastic energy in maximum. Our calculation shows that a bead in the concave region lowers its energy $\sim 20 k_B T$. For an axisymmetrical dumbbell vesicle, the local curvature energy density along the waist is equally of maximum, the beads can thus be distributed freely with varying separation distance.Comment: 12 pages, 2 figures. REVte

Metal-insulator transition and the Pr3+^{3+}/Pr4+^{4+} valence shift in (Pr1−y_{1-y}Yy_{y})0.7_{0.7}Ca0.3_{0.3}CoO3_3

The magnetic, electric and thermal properties of the ($Ln_{1-y}$Y$_{y}$)$_{0.7}$Ca$_{0.3}$CoO$_3$ perovskites ($Ln$~=~Pr, Nd) were investigated down to very low temperatures. The main attention was given to a peculiar metal-insulator transition, which is observed in the praseodymium based samples with $y=0.075$ and 0.15 at $T_{M-I}=64$ and 132~K, respectively. The study suggests that the transition, reported originally in Pr$_{0.5}$Ca$_{0.5}$CoO$_3$, is not due to a mere change of cobalt ions from the intermediate- to the low-spin states, but is associated also with a significant electron transfer between Pr$^{3+}$ and Co$^{3+}$/Co$^{4+}$ sites, so that the praseodymium ions occur below $T_{M-I}$ in a mixed Pr$^{3+}$/Pr$^{4+}$ valence. The presence of Pr$^{4+}$ ions in the insulating phase of the yttrium doped samples (Pr$_{1-y}$Y$_{y}$)$_{0.7}$Ca$_{0.3}$CoO$_3$ is evidenced by Schottky peak originating in Zeeman splitting of the ground state Kramers doublet. The peak is absent in pure Pr$_{0.7}$Ca$_{0.3}$CoO$_3$ in which metallic phase, based solely on non-Kramers Pr$^{3+}$ ions, is retained down to the lowest temperature.Comment: 10 figure

Evidence for a quantum phase transition in the electron-doped cuprate Pr2-xCexCuO4+d from Hall and resistivity measurements

The doping and temperature dependence of the Hall coefficient, RH, and ab-plane resistivity in the normal state down to 350mK is reported for oriented films of the electron-doped high-Tc superconductor Pr2-xCexCuO4+d. The doping dependence of b (r=r0+AT^b) and R_sub_H (at 350 mK) suggest a quantum phase transition at a critical doping near x=0.165.Comment: 11 pages 4 figures Phys. Rev. Lett. 92, 167001 (2004